"Detailed balance"의 두 판 사이의 차이
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===소스=== | ===소스=== | ||
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+ | == 메타데이터 == | ||
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+ | ===위키데이터=== | ||
+ | * ID : [https://www.wikidata.org/wiki/Q1201087 Q1201087] |
2020년 12월 26일 (토) 05:25 판
노트
위키데이터
- ID : Q1201087
말뭉치
- The principle of detailed balance was explicitly introduced for collisions by Ludwig Boltzmann.[1]
- In 1901, R. Wegscheider introduced the principle of detailed balance for chemical kinetics.[1]
- We develop a general framework for the discussion of detailed balance and analyse its microscopic background.[2]
- We briefly discuss examples of the violation of these rules and the corresponding violation of detailed balance.[2]
- The concept of detailed balance is central to the field of chemical kinetics and provides important constraints on relationships between equilibrium and rate constants.[3]
- The principle of detailed balance is shown to be a sufficient condition for the second law of thermodynamics in thermally equilibrated elementary chemical reactions.[4]
- For an elementary reaction, the principle of detailed balance relates the forward and the reverse rate constants through the reaction equilibrium constant.[4]
- As expected, this term vanishes when detailed balance holds and the current is zero (see Methods).[5]
- Transition rates between passive states obey local detailed balance: ω i,i+1 /ω i+1,i = eβFL, where L is the length of a single spatial jump.[5]
- The principle of detailed balance can be used in kinetic systems which are decomposed into elementary processes (collisions, or steps, or elementary reactions).[6]
- ⟶ A 1 {\displaystyle {\ce {A1->A2->\cdots ->A_{\mathit {n}}->A1}}} are impossible and found explicitly the relations between kinetic constants that follow from the principle of detailed balance.[6]
- Detailed balance for Boltzmann's equation requires PT-invariance of collisions' dynamics, not just T-invariance.[6]
- Detailed balance implies that, around any closed cycle of states, there is no net flow of probability.[6]
- According to the principle of detailed balance (Sect. 1.2), any reaction taking place within a thermal gas is exactly counterbalanced by its inverse reaction.[7]
- 1.4, detailed balance is used to derive the thermal distribution functions encountered in plasma spectroscopy.[7]
- As the principle of detailed balance is based on the reciprocity relation of the transition probabilities between quantum states, the validity of this latter relation is discussed in Sect. 1.5.[7]
- Detailed balance provides a technique to calculate the maximum efficiency of photovoltaic devices.[8]
- The calculations for detailed balance calculations involve calculating the particle flux for different configurations of the Plank’s equation.[8]
- We now show there are further problems in Feynman's treatment of detailed balance.[9]
- In order to design and understand this device correctly, the equations of detailed balance must be found.[9]
- In this Viewpoint, we developed a detailed balance analysis of PV windows in order to investigate the major design elements of PCE, VLT, SHGC, and color.[10]
- DOI: 10.1038/srep13536 20 Datas, A. ; Algora, C. Detailed balance analysis of solar thermophotovoltaic systems made up of single junction photovoltaic cells and broadband thermal emitters .[10]
- These are called the detailed balance equations.[11]
- In this study, we analyzed the nonradiative recombination impact of multiple exciton generation solar cells (MEGSCs) with a revised detailed balance (DB) limit.[12]
- Detailed balance is the balance of flows between any (and every) pair of states you care to define.[13]
- In fact, many common models of biochemistry exhbit "irreversible" steps - in which the reverse of some step never occurs - and could never satisfy detailed balance.[13]
- A Markov process preserves detailed balance if the ratio transition probability between any two states states is equal to the ratio of the probability of the states themselves.[14]
- The second test measures the detailed balance of the SidechainMover, which samples off-rotamer sidechain conformations.[14]
- Transitions between states obey a detailed balance in equilibrium, whereas imbalanced transitions point to nonequilibrium dynamics.[15]
- It is not true that MCMC fulfilling detailed balance always yield the stationary distribution.[16]
- AB - In this study, we analyzed the nonradiative recombination impact of multiple exciton generation solar cells (MEGSCs) with a revised detailed balance (DB) limit.[17]
- detailed balance condition is characterized by the property that this constant is identically zero.[18]
- We then give a second characterization of the dynamical detailed balance condition using a master equation rather than the microcurrents.[18]
- This is achieved using Markov chain transitions that satisfy the fixed point equation, but do not satisfy detailed balance.[19]
- We study an irreversible Markov chain Monte Carlo method based on a skew detailed balance condition for a one-dimensional Ising model.[20]
소스
- ↑ 1.0 1.1 29.2: The Principle of Detailed Balance
- ↑ 2.0 2.1 Detailed balance in micro- and macrokinetics and micro-distinguishability of macro-processes
- ↑ Comment: Detailed balance revisited
- ↑ 4.0 4.1 Principle of Detailed Balance and the Second Law of Thermodynamics in Chemical Kinetics
- ↑ 5.0 5.1 Inferring broken detailed balance in the absence of observable currents
- ↑ 6.0 6.1 6.2 6.3 Detailed balance
- ↑ 7.0 7.1 7.2 Thermal Equilibrium and Detailed Balance
- ↑ 8.0 8.1 Detailed Balance
- ↑ 9.0 9.1 Detailed balance of the Feynman micromotor
- ↑ 10.0 10.1 Detailed Balance Analysis of Photovoltaic Windows
- ↑ 14.1 Detailed Balance · GitBook
- ↑ Numerical Analysis of the Detailed Balance of Multiple Exciton Generation Solar Cells with Nonradiative Recombination
- ↑ 13.0 13.1 Equilibrium Means Detailed Balance
- ↑ 14.0 14.1 DetailedBalanceScientificBenchmark
- ↑ Broken detailed balance at mesoscopic scales in active biological systems
- ↑ Does a MCMC fulfilling detailed balance yields a stationary distribution?
- ↑ Numerical analysis of the detailed balance of multiple exciton generation solar cells with nonradiative recombination
- ↑ 18.0 18.1 DYNAMICAL DETAILED BALANCE AND LOCAL KMS CONDITION FOR NON-EQUILIBRIUM STATES
- ↑ Hamiltonian Monte Carlo Without Detailed Balance
- ↑ Dynamics of One-Dimensional Ising Model without Detailed Balance Condition
메타데이터
위키데이터
- ID : Q1201087