Detailed balance

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위키데이터

• ID : Q1201087

말뭉치

1. The principle of detailed balance was explicitly introduced for collisions by Ludwig Boltzmann.
2. In 1901, R. Wegscheider introduced the principle of detailed balance for chemical kinetics.
3. We develop a general framework for the discussion of detailed balance and analyse its microscopic background.
4. We briefly discuss examples of the violation of these rules and the corresponding violation of detailed balance.
5. The concept of detailed balance is central to the field of chemical kinetics and provides important constraints on relationships between equilibrium and rate constants.
6. The principle of detailed balance is shown to be a sufficient condition for the second law of thermodynamics in thermally equilibrated elementary chemical reactions.
7. For an elementary reaction, the principle of detailed balance relates the forward and the reverse rate constants through the reaction equilibrium constant.
8. As expected, this term vanishes when detailed balance holds and the current is zero (see Methods).
9. Transition rates between passive states obey local detailed balance: ω i,i+1 /ω i+1,i = eβFL, where L is the length of a single spatial jump.
10. The principle of detailed balance can be used in kinetic systems which are decomposed into elementary processes (collisions, or steps, or elementary reactions).
11. ⟶ A 1 {\displaystyle {\ce {A1->A2->\cdots ->A_{\mathit {n}}->A1}}} are impossible and found explicitly the relations between kinetic constants that follow from the principle of detailed balance.
12. Detailed balance for Boltzmann's equation requires PT-invariance of collisions' dynamics, not just T-invariance.
13. Detailed balance implies that, around any closed cycle of states, there is no net flow of probability.
14. According to the principle of detailed balance (Sect. 1.2), any reaction taking place within a thermal gas is exactly counterbalanced by its inverse reaction.
15. 1.4, detailed balance is used to derive the thermal distribution functions encountered in plasma spectroscopy.
16. As the principle of detailed balance is based on the reciprocity relation of the transition probabilities between quantum states, the validity of this latter relation is discussed in Sect. 1.5.
17. Detailed balance provides a technique to calculate the maximum efficiency of photovoltaic devices.
18. The calculations for detailed balance calculations involve calculating the particle flux for different configurations of the Plank’s equation.
19. We now show there are further problems in Feynman's treatment of detailed balance.
20. In order to design and understand this device correctly, the equations of detailed balance must be found.
21. In this Viewpoint, we developed a detailed balance analysis of PV windows in order to investigate the major design elements of PCE, VLT, SHGC, and color.
22. DOI: 10.1038/srep13536 20 Datas, A. ; Algora, C. Detailed balance analysis of solar thermophotovoltaic systems made up of single junction photovoltaic cells and broadband thermal emitters .
23. These are called the detailed balance equations.
24. In this study, we analyzed the nonradiative recombination impact of multiple exciton generation solar cells (MEGSCs) with a revised detailed balance (DB) limit.
25. Detailed balance is the balance of flows between any (and every) pair of states you care to define.
26. In fact, many common models of biochemistry exhbit "irreversible" steps - in which the reverse of some step never occurs - and could never satisfy detailed balance.
27. A Markov process preserves detailed balance if the ratio transition probability between any two states states is equal to the ratio of the probability of the states themselves.
28. The second test measures the detailed balance of the SidechainMover, which samples off-rotamer sidechain conformations.
29. Transitions between states obey a detailed balance in equilibrium, whereas imbalanced transitions point to nonequilibrium dynamics.
30. It is not true that MCMC fulfilling detailed balance always yield the stationary distribution.
31. AB - In this study, we analyzed the nonradiative recombination impact of multiple exciton generation solar cells (MEGSCs) with a revised detailed balance (DB) limit.
32. detailed balance condition is characterized by the property that this constant is identically zero.
33. We then give a second characterization of the dynamical detailed balance condition using a master equation rather than the microcurrents.
34. This is achieved using Markov chain transitions that satisfy the fixed point equation, but do not satisfy detailed balance.
35. We study an irreversible Markov chain Monte Carlo method based on a skew detailed balance condition for a one-dimensional Ising model.

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위키데이터

• ID : Q1201087